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There are many ways to make S.O.S. Battles more likely. encounter row and give you a Pokémon of the same slot in that row as the Pokémon you are facing.
You can do SOS chaining to get more Effort Value (EV) points, . if the on field synchronizer isn't at the first slot in your Pokémon party.
We still lack information about how additional SOS slots are chosen/can be chosen (those who contain Castrofm, Gabite,..), as well as.